Nanomaterials for sustainable remediation: efficient removal of Rhodamine B and lead using greenly synthesized novel mesoporous ZnO@CTAB nanocomposite.

This study explores the dual applications of a greenly synthesized ZnO@CTAB nanocomposite for the efficient remediation of Rhodamine B (RhB) and lead (Pb). The synthesis method involves a sustainable approach, emphasizing environmentally friendly practices. FT-IR, XRD, FESEM, zeta potential, and particle size analyzer (PSA), BET, and UV-VIS were used to physically characterize the zinc oxide and CTAB nanocomposite (ZnO@CTAB). The size and crystalline index of ZnO@CTAB are 77.941 nm and 63.56% respectively. The Zeta potential of ZnO@CTAB is about - 22.4 mV. The pore diameter of the ZnO@CTAB was 3.216 nm, and its total surface area was 97.42 m2/g. The mechanism of adsorption was investigated through pHZPC measurements. The nanocomposite's adsorption performance was systematically investigated through batch adsorption experiments. At pH 2, adsorbent dose of 0.025 g, and temperature 50 °C, ZnO@CTAB removed the most RhB, while at pH 6, adsorbent dose of 0.11 g, and temperature 60 °C, ZnO@CTAB removed the most Pb. With an adsorption efficiency of 214.59 mg/g and 128.86 mg/g for RhB and Pb, the Langmuir isotherm model outperforms the Freundlich isotherm model in terms of adsorption. The pseudo-2nd-order model with an R2 of 0.99 for both RhB and Pb offers a more convincing explanation of adsorption than the pseudo-1st-order model. The results demonstrated rapid adsorption kinetics and high adsorption capacities for RhB and Pb. Furthermore, there was minimal deterioration and a high reusability of ZnO@CTAB till 4 cycles were observed.

Sustainable approach for adsorptive removal of cationic and anionic dyes by titanium oxide nanoparticles synthesized biogenically using algal extract ofSpirulina.

Worldwide, dyes are significant pollutants present in water because of their huge consumption for industrial purposes. These dyes as pollutants cause serious health issues in human beings and cause the loss of aquatic biodiversity. So, remediation of pollutants like dyes from wastewater is the need of the hour. In the present study, we greenly synthesizedSpirulina-mediated titanium oxide nanoparticles (STONPs) for the adsorptive remediation of methyl orange (MO) (anionic) and malachite green (MG) (cationic) dyes. The characterization of STONPs was performed by Field emission scanning electron microscopy (FESEM) with EDX, FT-IR, XRD, Zeta Potential and particle size analyzer, Raman spectroscopy, and UV-vis. The various parameter effects like pH, nano-adsorbent dose, the concentration of dye, contact time, and temperature were also examined. Adsorption isotherms like Langmuir, Freundlich, and Temkin, and Kinetics models like Elovich Model, Pseudo 1st, intraparticle diffusion model (IPDM), Pseudo 2nd order, and the thermodynamic model were applied for a stronger interpretation. Theqmaxattained utilizing the Langmuir adsorption model was 272.4795 mg g-1and 209.6436 mg g-1for MO and MG correspondingly. The regeneration study of synthesized nanomaterials up to five cycles was also done. We found that greenly synthesized STONPs have great potential for adsorptive remediation for both MG and MO dyes.

Unveiling the microbial diversity and functional dynamics of Shiv Kund, Sohna hot spring, India through a shotgun metagenomics approach.

In this research, we examined the microbial diversity in Sohna hot spring, Haryana, India using shotgun metagenome sequencing based on the Illumina Hiseq 4000 sequencing technology. The raw sequence data from metagenomic paired-end libraries were analysed for taxonomic classification, diversity, and functional annotation using MG-RAST online server. The results showed the presence of total of 57 phyla, 931 genera, and 2068 species, predominantly occupied by Moraxellaceae (Gammaproteobacteria). However, at the species level, we reported the presence of some representative pathogenic taxa, such as Acinetobacter baumannii and Moraxella osloensis. The functional annotation predicted at various levels based on SEED-based subsystem, KEGG ortholog identity (KO), Cluster of Orthologous Groups (COGs) database identified the predominance of genes associated with primary and secondary metabolism along with a crucial role in environmental and genetic signals, cellular communication, and cell signalling. Comparative Genome Analysis (CGA) using The Pathosystem Resource Integration Centre (PATRIC) tool based on genome annotation and assembly of the metagenomic libraries for representative taxon Acinetobacter baumannii (NCBI tax id:470) characterized the reads with a unique genome identifier of 470.20380 (A. baumannii DDLJ4) which is evolutionary closer to A. baumannii ATCC 470.17978 400667.7. In addition, the CARD database results about the presence of potential AMR pathotypes and the prevalence of adeABC, adeIJK, abeM gene-specific clusters that function as multidrug efflux pumps. Overall, the results provided a comprehensive insight into virulence and anti-microbial resistance mechanism and could be useful for developing potential drug targets against the possible AMR pathotypes.

Remediation of contaminants from wastewater using algal nanoparticles via green chemistry approach: an organized review.

Bio-nanotechnology is one of the new and sound techniques that have various advantages over conventional methods of wastewater treatment. The utilization of nanomaterials like nanoparticles for wastewater treatment is emerging field of research. Both physical and chemical methods can be used for nanoparticle synthesis, but synthesis based on algae (biological method) has numerous advantages over others as it is environmentally friendly and sustainable. Top-down and bottom-up are the two approaches used for nanoparticle synthesis, generally, bio-reduction (bottom-up approach) is used to synthesize nanoparticles. Nanoparticles can be synthesized inside the cell of algae called intracellular synthesis and outside on the surface of the cell called extracellular synthesis. Temperature, pH, and reaction time are some of the factors that can influence the synthesis, size, and properties of nanoparticles. Characterization of nanoparticles is carried out with the help of the techniques like UV-visible spectroscopy (UV-vis), x-ray diffraction, Fourier transfer infrared spectroscopy, etc. Algal nanoparticles are highly efficient in the remediation of contaminants like heavy metals and dyes from wastewater. In the present review, the utilization of algal nanoparticles for wastewater treatment containing contaminants like heavy metals, and dye, and various methods of synthesis of nanoparticles from algae are discussed. Moreover, the challenges and opportunities present in this field are also highlighted. As this field is in its initial stage, therefore, a lot of research gaps are present, which can only be filled by further new research.

Determining groundwater quality using indices and multivariate statistical techniques: a study of Tosham block, Haryana, India.

Water is the most important component for human survival and often the most misused one. The present study deals with the assessment of groundwater quality of Tosham block, Bhiwani District, Haryana, India, and its nearby villages. A total of 23 samples were collected from different groundwater sources and were analysed for 16 different physico-chemical parameters. Correlation coefficients were calculated to identify highly correlated and interrelated water quality parameters. It provides an excellent tool for the prediction of parameter values within the reasonable rank of exactness. A strong correlation was observed between total hardness, magnesium and total dissolved solids, especially between total dissolved solids and electrical conductivity. The obtained results were compared with Indian Standard Drinking water specifications IS: 10500-2012. Concentration of total hardness, iron and chloride was found above the permissible limit in all the samples. Multivariate statistical techniques, namely cluster analysis and principal component analysis, were used to find the relationship between studied parameters. Water quality index (WQI) was also calculated. The WQI of groundwater samples ranged from 125 to 556. The water quality index revealed that out of 23 samples, 13 were found to have poor water quality and 6 samples were of very poor water quality. High value of WQI was found mainly from total dissolved solids, electrical conductivity, total hardness, Mg, Cl and Fe. Groundwater analysis of the studied water samples indicated that there is a need to treat the water before its use for drinking and other domestic activities. Necessary precautions should be taken to prevent the groundwater from being contaminated.

Towards sustainable agriculture with carbon sequestration, and greenhouse gas mitigation using algal biochar.

With the increase in the world's population, demand for food and other products is continuously rising. This has put a lot of pressure on the agricultural sector. To fulfill these demands, the utilization of chemical fertilizers and pesticides has also increased. Consequently, to overcome the adverse effects of agrochemicals on our environment and health, there has been a shift towards organic fertilizers or other substitutes, which are ecofriendly and help to maintain a sustainable environment. Microalgae have a very high potential of carbon dioxide (CO2) capturing and thus, help in mitigating the greenhouse effect. It is the most productive biological system for generating biomass. The high growth rate and higher photosynthetic efficiency of the algal species compared to the terrestrial plants make them a wonderful alternative towards a sustainable environment. Moreover, they could be cultivated in photobioreactors or open ponds, which in turn reduce the demand for arable land. Biochar derived from algae is high in nutrients and exhibits the property of ion exchange. Therefore, it can be utilized for sustainable agriculture by partial substituting the chemical fertilizers that degrade the fertility of the soil in the long run. This review provides a detailed insight on the properties of algal biochar as a potential fertilizer for sustainable agriculture. Application of algal biochar in bio-refinery and its economic aspects, challenges faced and future perspective are also discusses in this study.

Green technology for sustainable biohydrogen production (waste to energy): A review.

Perceiving and detecting a sustainable source of energy is very critical issue for current modern society. Hydrogen on combustion releases energy and water as a byproduct and has been considered as an environmental pollution free energy carrier. From the last decade, most of the researchers have recommended hydrogen as one of the cleanest fuels and its demand is rising ever since. Hydrogen having the highest energy density is more advantageous than any other fuel. Hydrogen obtained from the fossil fuels produces carbon dioxide as a byproduct and creates environment negative effect. Therefore, biohydrogen production from green algae and cyanobacteria is an attractive option that generates a benign renewable energy carrier. Microalgal feedstocks show a high potential for the generation of fuel such as biohydrogen, bioethanol and biodiesel. This article has reviewed the different methods of biohydrogen production while also trying to find out the most economical and ecofriendly method for its production. A thorough review process has been carried out to study the methods, enzymes involved, factors affecting the rate of hydrogen production, dual nature of algae, challenges and commercialization potential of algal biohydrogen.

Perspectives on ICD-11 to understand and improve mental health diagnosis using expertise by experience (INCLUDE Study): an international qualitative study.

Developed in collaboration with WHO Department of Mental Health and Substance Abuse, this study (conducted in India, the UK, and the USA) integrated feedback from mental health service users into the development of the chapter on mental, behavioural, and neurodevelopmental disorders for ICD-11. The ICD-11 will be used for health reporting from January, 2022. As a reporting standard and diagnostic classification system, ICD-11 will be highly influential by informing policy, clinical practice, and research that affect mental health service users. We report here the first study to systematically seek and collate service user perspectives on a major classification and diagnostic guideline. Focus groups were used to collect feedback on five diagnoses: depressive episode, generalised anxiety disorder, schizophrenia, bipolar type 1 disorder, and personality disorder. Participants were given the official draft diagnostic guidelines and a parallel lay translation. Data were then thematically analysed, forming the basis of co-produced recommendations for WHO, which included features that could be added or revised to better reflect lived experience and changes to language that was confusing or objectionable to service users. The findings indicated that an accessible lay language version of the ICD-11 could be beneficial for service users and their supporters.

Levels and sources of organic compounds in fine ambient aerosols over National Capital Region of India.

The study presents the spatial and temporal variation of fine ambient aerosols (PM2.5) over National Capital Region (NCR), India, during January to June 2016. The investigation includes three sampling sites, one in Delhi and two in the adjoining states of Delhi (Uttar Pradesh and Haryana), across NCR, India. The average PM2.5 concentration was highest for Delhi (128.5 ± 51.5 µg m-3) and lowest for Mahendragarh, Haryana (74.5 ± 28.7 µg m-3), during the study period. Seasonal variation was similar for all the sites with highest concentration during winter and lowest in summer. PM2.5 samples were analysed for organic compounds using gas chromatograph (GC). The concentration of three organic compound classes, n-alkanes (C11-C35), polycyclic aromatic hydrocarbons (PAHs), and phthalates, present in PM2.5 samples has been reported. Diagnostic ratios for n-alkanes demonstrated that biogenic emissions were dominant over Mahendragarh while major contributions were observed from petrogenic emissions over Delhi and Modinagar, Uttar Pradesh. Molecular diagnostic ratios were calculated to distinguish between different sources of PAHs, which revealed that the fossil fuel combustion (diesel and gasoline emissions), traffic emissions, and biomass burning are the major source contributors. Health risk associated with human exposure of phthalates and PAHs was also assessed as daily intake (DI, ng kg-1 day-1) and lung cancer risk, respectively. Backward trajectory analysis explained the local, regional, and long-range transport routes of PM2.5 for all sites. Principal component analysis (PCA) results summarized that the vehicular emissions, biomass burning, and plastic burning were the major sources of the PAHs and phthalates over the sampling sites.

Unduly extensive uncinate process of pancreas in conjunction with pancreatico-duodenal fold / 대한해부학회지

Anatomical variations of pancreatic head and uncinate process are rarely encountered in clinical practice. These variations are primarily attributed to the complex development of the pancreas. An unduly enlarged uncinate process of the pancreas overlapping the third part of duodenum was discovered during dissection. This malformation of the pancreatic uncinate process was considered to be due to excessive fusion between the ventral and dorsal buds during embryonic development. On further dissection, an avascular pancreatico-duodenal fold guarding the pancreatico-duodenal recess was observed. The enlarged uncinate process can cause compression of neurovascular structures and also cause compression of adjoining viscera. The pancreatico-duodenal recess becomes a potential site for internal herniation. This case is of particular interest to the gastroenterologists and surgeons performing surgical resections. Precise knowledge of embryogenesis of such pancreatic anomalies is necessary for understanding and thus treating many diseases of the pancreas.

Integrating photobiological hydrogen production with dye-metal bioremoval from simulated textile wastewater.

The study reports production of hydrogen in photobioreactors with free (PBR(Fr)) and immobilized (PBR(Imm)) Nostoc biomass at enhanced and sustained rates. Before running the photobioreactors, effects of different immobilization matrices and cyanobacterial dose on hydrogen production were studied in batch mode. As hydrogen production in the PBRs declined spent biomass from the photobioreactors were collected and utilized further for column biosorption of highly toxic dyes (Reactive Red 198+Crystal Violet) and metals (hexavalent chromium and bivalent cobalt) from simulated textile wastewater. Breakthrough time, adsorption capacity and exhaustion time of the biosorption column were studied. The photobioreactors with free and immobilized cyanobacterium produced hydrogen at average rates of 101 and 151 µmol/h/mg Chl a, respectively over 15 days, while the adsorption capacity of the spent biomass was up to 1.4 and 0.23 mg/g for metals and 15 and 1.75 mg/g for the dyes, respectively in continuous column mode.

Hydrogen production and metal-dye bioremoval by a Nostoc linckia strain isolated from textile mill oxidation pond.

Biohydrogen production by Nostoc linckia HA-46, isolated from a textile-industry oxidation-pond was studied by varying light/dark period, pH, temperature and ratio of carbon-dioxide and argon in the gas-mixture. Hydrogen production rates were maximum under 18 h of light and 6 h of darkness, pH 8.0, 31°C, a CO(2):Ar ratio 2:10. Hydrogen production of the strain acclimatized to 20 mg/L of chromium/cobalt and 100 mg/L of Reactive red 198/crystal violet dye studied in N-supplemented/deficient medium was 6-10% higher in the presence of 1.5 g/L of NaNO(3). Rates of hydrogen production in the presence of dyes/metals by the strain (93-105 µmol/h/mg Chlorophyll) were significantly higher than in medium without metals/dyes serving as control (91.3 µmol/h/mg Chlorophyll). About 58-60% of the two metals and 35-73% of dyes were removed by cyanobacterium. Optimal conditions of temperature, pH and metals/dyes concentration for achieving high hydrogen production and wastewater treatment were found practically applicable as similar conditions are found in the effluent of regional textile-mills.